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Synthesis and Applications of SnO Nanosheets: Parallel Control of Oxidation State and Nanostructure Through an Aqueous Solution Route
Author(s) -
Sakaushi Ken,
Oaki Yuya,
Uchiyama Hiroaki,
Hosono Eiji,
Zhou Haoshen,
Imai Hiroaki
Publication year - 2010
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.200902207
Subject(s) - materials science , aqueous solution , photocurrent , chemical engineering , nanostructure , tin , anode , tin oxide , indium tin oxide , nanofiber , thin film , nanotechnology , oxide , electrode , optoelectronics , organic chemistry , chemistry , engineering , metallurgy
Abstract Tin monoxide (SnO) nanosheets 5 nm in thickness are generated on substrates through an aqueous solution process under mild conditions. Parallel control of the oxidation state and morphology is achieved by a urea‐mediated approach in aqueous solution. The SnO nanosheets form a porous thin film on substrates such as indium tin oxide and carbon nanofiber (CNF). The porous thin film of SnO nanosheets shows cathodic photocurrent generation upon irradiation by UV and visible light. In contrast, the photocurrent is not observed in the bulk SnO microcrystals. Composites of the SnO nanosheets and CNF perform as the anode material of lithium‐ion batteries with improved charge–discharge reversible stability.