Molecular Design of Heteroprotein Assemblies Providing a Bionanocup as a Chemical Reactor | Zendy

Koshiyama Tomomi | Zendy; Yokoi Norihiko | Zendy; Ueno Takafumi | Zendy; Kanamaru Shuji | Zendy; Nagano Shingo | Zendy; Shiro Yoshitsugu | Zendy; Arisaka Fumio | Zendy; Watanabe Yoshihito | Zendy

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Molecular Design of Heteroprotein Assemblies Providing a Bionanocup as a Chemical Reactor

Author(s) -

Koshiyama Tomomi,

Yokoi Norihiko,

Ueno Takafumi,

Kanamaru Shuji,

Nagano Shingo,

Shiro Yoshitsugu,

Arisaka Fumio,

Watanabe Yoshihito

Publication year - 2008

Publication title -

small

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.785

H-Index - 236

eISSN - 1613-6829

pISSN - 1613-6810

DOI - 10.1002/smll.200700855

Subject(s) - porphyrin , solubility , catalysis , composite number , materials science , chemical engineering , chemistry , combinatorial chemistry , nanotechnology , organic chemistry , composite material , engineering

A bionanocup chemical reactor is constructed from a heteroprotein assembly from bacteriophage T4. The preparation of a stable iron(III) porphyrin–bionanocup composite is described. The hydrophobic cup provides a space suitable for the fixation of low‐water‐solubility iron(III) porphyrins. The application of the iron(III) porphyrin–bionanocup composites for the catalysis of sulfoxidation of thioanisoles is demonstrated (see figure).

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