Patterned Polymer Brushes Grafted from Bromine‐Functionalized, Chemically Active Surface Templates | Zendy

Becer C. Remzi | Zendy; Haensch Claudia | Zendy; Hoeppener Stephanie | Zendy; Schubert Ulrich S. | Zendy

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Patterned Polymer Brushes Grafted from Bromine‐Functionalized, Chemically Active Surface Templates

Author(s) -

Becer C. Remzi,

Haensch Claudia,

Hoeppener Stephanie,

Schubert Ulrich S.

Publication year - 2007

Publication title -

small

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.785

H-Index - 236

eISSN - 1613-6829

pISSN - 1613-6810

DOI - 10.1002/smll.200600234

Subject(s) - template , bromine , materials science , polymer , surface modification , nanotechnology , polymer chemistry , polymer science , chemical engineering , composite material , engineering , metallurgy

Patterned polymer films are grafted from chemically active surface templates prepared by the localized electrochemical oxidation of an n ‐octadecyltrichlorosilane monolayer to form addressable areas for the site‐selective binding of a bromine‐terminated precursor. Atom‐transfer radical polymerization of polystyrene generated stable, patterned polymer structures of different shapes and dimensions (see image). Electroprinting was used to generate features in the micro/millimeter range.

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