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An Unexpected C‐S Bond Transformation with High Chemoselectivity for the Synthesis of Aryl‐Benzyl Sulfones
Author(s) -
Liu Teng,
Shen Xianfu,
Liu Zining,
Shi Rong,
Wei Wen,
Xu Yanli,
Cheng Feixiang
Publication year - 2021
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202102247
Subject(s) - chemoselectivity , aryl , transformation (genetics) , combinatorial chemistry , chemistry , catalysis , organic chemistry , alkyl , biochemistry , gene
In this report, an unexpected C−S bond transformation involving a high chemoselectivity between sulfonylhydrazides and dibenzyl phosphite catalyzed by NaI under mild conditions has been developed. This alternative protocol could provide a metal‐free route to access a diverse aryl‐benzyl sulfones in good to excellent yields.

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