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Polyaniline‐Supported Tungsten‐Catalyzed Green and Selective Oxidation of Alcohols
Author(s) -
Sun Hong,
Shi Yaocheng,
Fu Weijun,
Yu Lei
Publication year - 2021
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202101934
Subject(s) - polyaniline , catalysis , tungsten , alcohol oxidation , selectivity , salt (chemistry) , alcohol , chemistry , primary (astronomy) , nitrogen , inorganic chemistry , organic chemistry , polymer chemistry , materials science , polymer , physics , astronomy , polymerization
Polyaniline (PANI)‐supported tungsten could be easily fabricated by immersing PANI into the tungsten salt solution. It was a high efficient catalyst for alcohol oxidation reaction to produce carbonyls. Notably, the selectivities of the oxidation of primary alcohols were good, affording aldehydes as the specific products. The high catalytic activity might attribute to the coordination of nitrogen in PANI with tungsten in the materials, while the unique structure afforded the catalyst high selectivity for primary alcohol oxidation.