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Wacker‐Tsuji‐Type Oxidation Reactions of Styrene Derivatives Catalyzed by Ferrate
Author(s) -
Hashimoto Toru,
Maruyama Tsubasa,
Ishimaru Toshiya,
Matsugaki Masaru,
Shiota Keisuke,
Yamaguchi Yoshitaka
Publication year - 2021
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202101752
Subject(s) - styrene , catalysis , yield (engineering) , chemistry , wacker process , bond cleavage , organic chemistry , polymer chemistry , copolymer , materials science , palladium , polymer , metallurgy
We have developed a Wacker‐Tsuji‐Type oxidation reaction of styrene derivatives catalyzed by a bench‐stable ferrate. This oxidation reaction, which uses molecular oxygen as the sole oxidant and 1,1,3,3‐tetramethyldisiloxane (TMDS) as a reductant, can realize the oxidation of styrene derivatives to ketones in good yield. In addition, this ferrate‐based system can achieve the cleavage of the C−C double bond of α‐phenyl‐substituted styrene derivatives, providing the one‐carbon‐degraded ketones in good yield.