Wacker‐Tsuji‐Type Oxidation Reactions of Styrene Derivatives Catalyzed by Ferrate | Zendy

Hashimoto Toru | Zendy; Maruyama Tsubasa | Zendy; Ishimaru Toshiya | Zendy; Matsugaki Masaru | Zendy; Shiota Keisuke | Zendy; Yamaguchi Yoshitaka | Zendy

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Wacker‐Tsuji‐Type Oxidation Reactions of Styrene Derivatives Catalyzed by Ferrate

Author(s) -

Hashimoto Toru,

Maruyama Tsubasa,

Ishimaru Toshiya,

Matsugaki Masaru,

Shiota Keisuke,

Yamaguchi Yoshitaka

Publication year - 2021

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.202101752

Subject(s) - styrene , catalysis , yield (engineering) , chemistry , wacker process , bond cleavage , organic chemistry , polymer chemistry , copolymer , materials science , palladium , polymer , metallurgy

We have developed a Wacker‐Tsuji‐Type oxidation reaction of styrene derivatives catalyzed by a bench‐stable ferrate. This oxidation reaction, which uses molecular oxygen as the sole oxidant and 1,1,3,3‐tetramethyldisiloxane (TMDS) as a reductant, can realize the oxidation of styrene derivatives to ketones in good yield. In addition, this ferrate‐based system can achieve the cleavage of the C−C double bond of α‐phenyl‐substituted styrene derivatives, providing the one‐carbon‐degraded ketones in good yield.

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