Oxidation of Silanes to Silanols with Oxygen via Photoredox Catalysis | Zendy

Li Jiayan | Zendy; Xu Dandan | Zendy; Shi Guangrui | Zendy; Liu Xingyuan | Zendy; Zhang Jianqiang | Zendy; Fan Baomin | Zendy

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Oxidation of Silanes to Silanols with Oxygen via Photoredox Catalysis

Author(s) -

Li Jiayan,

Xu Dandan,

Shi Guangrui,

Liu Xingyuan,

Zhang Jianqiang,

Fan Baomin

Publication year - 2021

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.202101241

Subject(s) - silanes , catalysis , photoredox catalysis , substrate (aquarium) , chemistry , yield (engineering) , photochemistry , oxygen , reaction mechanism , organic chemistry , photocatalysis , materials science , silane , oceanography , metallurgy , geology

An efficient method for the oxidation of silanes to silanols with oxygen is described. The reaction proceeded under the catalysis of the photoredox catalyst Ru(bpy) 3 Cl 2 .6H 2 O by irradiation with 30 W blue LED. The reaction exhibited good substrate scope with up to 88 % yield. The applicability of the present methodology is demonstrated by gram scale synthesis. A plausible reaction mechanism is also proposed.

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