Free Radical Polymerization of  o ‐Carborane Functionalized Styrene: Effect of Substitution Position at Carbon and Boron | Zendy

Wen XinYu | Zendy; Cao Ke | Zendy; Wu Ji | Zendy; Zhang CaiYan | Zendy; Li Xia | Zendy; Jiang Linhai | Zendy; Yang Junxiao | Zendy

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Free Radical Polymerization of o ‐Carborane Functionalized Styrene: Effect of Substitution Position at Carbon and Boron

Author(s) -

Wen XinYu,

Cao Ke,

Wu Ji,

Zhang CaiYan,

Li Xia,

Jiang Linhai,

Yang Junxiao

Publication year - 2021

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.202100932

Subject(s) - carborane , polymerization , styrene , boron , polymer chemistry , chemistry , radical polymerization , copolymer , polymer , organic chemistry

The AIBN initiated radical polymerization of o ‐carborane functionalized styrenes has been developed. The styrene decorated on the cage boron or cage carbon vertex of o ‐carboranes were all compatible with this polymerization. The M w of the desired P[4‐(B3‐ o ‐carborane)‐styrene] and P[C1‐methylene‐ o ‐carborane‐4‐vinylbenzene] could up to 3.5×10 5 and 1.7×10 5 , respectively. This work offers an efficient method for synthesis of o ‐carborane functionalized polystyrenes, which has important reference for synthesis of o ‐carborane containing polymers.

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