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Laccase‐Mimicking Syntheses of Phenoxazinones by Aerobic Oxidative Homo‐ and Hetero‐Dimerizations of Aminophenols
Author(s) -
Duan Wenxue,
Li Wenhao,
Tang Qingxuan,
Zhao Yiyang,
Guo Xianji,
Yang Guanyu
Publication year - 2021
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202100725
Subject(s) - laccase , chemistry , gallic acid , oxidative phosphorylation , organic chemistry , enzyme , biochemistry , antioxidant
To pursue a sustainable enzyme‐liking approach, a laccase‐mimicking model that utilized natural low‐toxic gallic acid as an organocatalyst was developed for efficient aerobic oxidative homo‐ and hetero‐dimerizations of various 2‐aminophenols to afford 2‐aminophenoxazin‐3‐ones with moderate to high isolated yields at room temperature in water.