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A Green CeO 2 −WO 3 /TiO 2 Medium‐Low Temperature de‐NO x Catalyst for Selective Catalytic Reduction of NO x with NH 3
Author(s) -
Fu Zihao,
Zhang Guodong,
Tang Zhicheng,
Zhang Haitao
Publication year - 2021
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202100598
Subject(s) - catalysis , cerium , selective catalytic reduction , materials science , tungsten , atmospheric temperature range , crystallization , inorganic chemistry , titanium dioxide , sulfur , precipitation , nuclear chemistry , chemistry , metallurgy , biochemistry , physics , meteorology , organic chemistry
A series of CeO 2 −WO 3 /TiO 2 catalysts were synthesized by the co‐precipitation method and used for selective catalytic reduction (SCR) of NO with NH 3 under medium‐low temperature conditions with metatitanic acid as Ti source. A more reasonable weight ratio of CeO 2 and WO 3 was explored. The catalytic activity enhanced with the increase of cerium content, but the catalytic activity changed slightly in the temperature range of 240 °C to 400 °C when the cerium content exceeded 15 %. Tungsten could enhance the sulfur resistance by adjusting the degree of crystallization, acidity in the SCR process. When the weight ratio of CeO 2 to WO 3 was 15: 8, the conversion rate of NO was more than 90 % in the temperature range of 240 °C to 440 °C. For 15 %CeO 2 ‐8 %WO 3 /TiO 2 catalyst, the NO conversion was maintained around 84 % when the mixed gas was introduced SO 2 . At the same time, we have optimized the selection of carriers, metatitanic acid as a carrier was better than titanium dioxide.
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