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Tandem Conjugate Addition/Aromatization/Acyl Transfer Reaction between 3‐Aryl‐2‐nitropropanoates and Quinone Monoimines
Author(s) -
Cheng ShaoBing,
Liu Hui,
Jing Yi,
Cao LianYi,
Zhang XiaoMei
Publication year - 2021
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202100557
Subject(s) - aromatization , conjugate , chemistry , quinone , tandem , aryl , reaction mechanism , cascade reaction , stereochemistry , organic chemistry , catalysis , materials science , mathematics , mathematical analysis , alkyl , composite material
A tandem conjugate addition/aromatization/acyl transfer reaction between 3‐aryl‐2‐nitropropanoates and quinone monoimines was described. In the presence of NMM, the reaction proceeded smoothly to give various 1,2‐diarylnitroethanes in low to good yields. The structure of one product was determined by an X‐ray crystal structural analysis. Accordingly, a plausible reaction mechanism was proposed.