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Mechanochemically Induced Chalcogenation of Bicyclic Arenes under Solvent‐, Ligand‐, Metal‐, and Oxidant‐Free Conditions
Author(s) -
Panja Subir,
Paul Biprajit,
Jalal Swapnadeep,
Ghosh Tubai,
Ranu Brindaban C.
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202003892
Subject(s) - bicyclic molecule , ligand (biochemistry) , catalysis , substrate (aquarium) , solvent , chemistry , metal , combinatorial chemistry , ball mill , organic solvent , organic chemistry , materials science , chemical engineering , metallurgy , biochemistry , oceanography , receptor , engineering , geology
A convenient method has been developed for the synthesis of biarenyl chalcogenides through the interaction of bicyclic arenes and diaryl dichalcogenides on the surface of basic alumina under ball milling without any metal catalyst or solvent. This methodology shows wide substrate scope and is of high potential in organic synthesis due to its green aspects of ease of operation, shorter reaction time, ambient conditions and high yields.