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P‐doped Carbon as the Efficient Support of Nickel Catalysts for Hydrodechlorination of Chlorodifluoromethane
Author(s) -
Zheng Qifu,
Wei Xiaoli,
Li Xiliang,
Liu Bing,
Chen Aimin,
Tang Haodong,
Han Wenfeng
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202002974
Subject(s) - heteroatom , catalysis , nickel , carbon fibers , doping , dispersion (optics) , materials science , inorganic chemistry , nuclear chemistry , chemistry , organic chemistry , metallurgy , optoelectronics , composite material , optics , ring (chemistry) , physics , composite number
P‐doped carbon material (P−C) is successfully fabricated through directly combust phytic acid via microwave assistant. Then the as‐made P−C is selected as the support to load various amount of Ni. As the evaluated results show that 5 %Ni/P−C exhibits better catalytic performance than 5 %Ni/C for chlorodifluoromethane hydrodechlorination (HDC) reaction. It is because that the doped‐P is feasible to promote the dispersion of Ni species on the surface of P−C through the strong interaction between Ni and the P−C support. Therefore, combining the synergetic effect between Ni and heteroatom‐doped carbon could provide a promising way to improve the activity of HDC reaction.