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Magnetic Properties of Metal Clusters Coordinated with (Nitronyl Nitroxide)‐Substituted Amidinate Ligands
Author(s) -
Tanimoto Ryu,
Suzuki Shuichi,
Kozaki Masatoshi,
Kanzaki Yuki,
Shiomi Daisuke,
Sato Kazunobu,
Takui Takeji,
Tanaka Rika,
Okada Keiji
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202002927
Subject(s) - chemistry , nitroxide mediated radical polymerization , cluster (spacecraft) , intramolecular force , metal , copper , crystallography , amidine , nucleophile , ligand (biochemistry) , polymer chemistry , photochemistry , inorganic chemistry , stereochemistry , polymerization , organic chemistry , polymer , catalysis , radical polymerization , biochemistry , receptor , computer science , programming language
We prepared dicopper, disilver, and tetragold clusters ligated with (nitronyl nitroxide)‐substituted amidinate (NN‐amidinate). NN‐substituted amidine was prepared from N , N ′‐diphenylcarbodiimide via a nucleophilic reaction with nitronyl nitroxide as a radical anion. The NN‐amidinate ligand was generated by treatment with an appropriate base, and subsequent addition of copper(I), silver(I), or gold(I) sources gave the respective metal cluster systems of Cu 2 ‐(NN‐amidinate) 2 , Ag 2 ‐(NN‐amidinate) 2 , or Au 4 ‐(NN‐amidinate) 4 . These radical‐metal clusters exhibited excellent stability, even in solution under aerated conditions, making them easy to handle. Single crystals were obtained by recrystallization from suitable solvent systems. The spin structures of the cluster systems were investigated by ESR spectroscopy and magnetic susceptibility measurements, which indicated the existence of weak intramolecular, spin‐spin interactions between the NN moieties.