Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines | Zendy

Pan JiaSheng | Zendy; Zhang Rui | Zendy; Ma ShuangShuang | Zendy; Han LiJun | Zendy; Xu BaoHua | Zendy

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Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

Author(s) -

Pan JiaSheng,

Zhang Rui,

Ma ShuangShuang,

Han LiJun,

Xu BaoHua

Publication year - 2020

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.202002795

Subject(s) - reductive amination , amination , ruthenium , primary (astronomy) , ammonia , catalysis , chemistry , intramolecular force , selectivity , organic chemistry , amine gas treating , combinatorial chemistry , physics , astronomy

An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H 2 and ammonia. The intramolecular carboxylate‐assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.

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