Premium
(−)‐β‐Pinene‐based π‐Allylpalladium Complex‐Catalyzed Asymmetric Allylation of Bis‐Imines
Author(s) -
Fernandes Rodney A.,
Nallasivam Jothi L.
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202002599
Subject(s) - pinene , catalysis , chemistry , enantioselective synthesis , medicinal chemistry , organic chemistry
(−)‐β‐Pinene‐based η 3 ‐π‐allylpalladium complex has shown the efficacy in the catalytic asymmetric allylation of para ‐ and meta ‐xylene spaced bis‐arylimines. The complex has catalyzed asymmetric allylation of various bis‐imines in the presence of allyltributylstannane and two equivalents of water to furnish chiral bis‐homoallylamines in moderate to good yields (up to 70%) and enantioselectivities up to 98.6 : 1.4 er.