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3D Foam Anode and Hydrogel Electrolyte for High‐Performance and Stable Flexible Zinc–Air Battery
Author(s) -
Qu Shengxiang,
Liu Bin,
Fan Xiayue,
Liu Xiaorui,
Liu Jie,
Ding Jia,
Han Xiaopeng,
Deng Yida,
Hu Wenbin,
Zhong Cheng
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202002573
Subject(s) - electrolyte , anode , materials science , chemical engineering , battery (electricity) , zinc , electrochemistry , electroplating , galvanic anode , electrode , composite material , layer (electronics) , chemistry , metallurgy , cathodic protection , power (physics) , physics , quantum mechanics , engineering
The development of flexible zinc–air battery (ZAB) is highly desirable in achieving superior and stable electrochemical/mechanical properties. Herein, we developed a Zn‐coated foam anode with three‐dimensional (3D) architecture, obtained by electroplating Zn on Cu foam substrate. The compact outer surface and sufficient amount of metallic Zn could be controlled accurately by selecting appropriate porous substrate and electroplating time on Cu foam. Moreover, adding tetraethylammonium hydroxide (TEAOH) to conventional polyvinyl alcohol (PVA)–KOH hydrogel electrolyte effectively improved the water retention of the semi‐solid electrolyte with stable ionic conductivity. The electrolyte precursor fluid was poured on the uneven outer surface of Zn‐coated foam anode and then frozen crosslinked to increase contact between the 3D anode and the electrolyte. A flexible semi‐solid‐state ZAB based on the 3D Zn‐coated foam anode and the hydrogel electrolyte was assembled and exhibited good discharge performance, high energy density (586.5 Wh kg Zn −1 ) and long cycling life. Benefiting from the flexibility of all components, the resultant ZAB performed stable charge and discharge under bending conditions, indicating its promising potential application for flexible and portable energy storage devices.