Synthesis of New Siloxane‐Containing Polyamide Based on Limonene and Comparison of Their Properties with Non‐Siloxane Analog | Zendy

Drozdov Fedor V. | Zendy; Tarasenkov Alexander N. | Zendy; Parshina Maria S. | Zendy; Cherkaev Georgii V. | Zendy; Buzin Mikhail I. | Zendy; Muzafarov Aziz M. | Zendy

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Synthesis of New Siloxane‐Containing Polyamide Based on Limonene and Comparison of Their Properties with Non‐Siloxane Analog

Author(s) -

Drozdov Fedor V.,

Tarasenkov Alexander N.,

Parshina Maria S.,

Cherkaev Georgii V.,

Buzin Mikhail I.,

Muzafarov Aziz M.

Publication year - 2020

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.202002250

Subject(s) - siloxane , polyamide , hexamethylenediamine , monomer , disiloxane , polymer chemistry , polymer , thermal stability , materials science , organic chemistry , chemistry , catalysis

For the first time, diacid derivative of limonene was obtained by thiol‐ene reaction with mercaptoacetic acid and it was further used as a monomer for the synthesis of polyamides. Commercially available hexamethylenediamine and its siloxane analogue, bis(aminopropyl) tetramethyl disiloxane, were used as diamines monomers. It was shown that the introduction of a siloxane unit into the structure of a polyamide chain increases the molecular weight and thermal stability of the polymer (more than 300 °C), and also affects its phase behavior at room temperature.

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