Potassium Iodide as a New Nucleophilic Catalyst for the Novel Synthesis of Ionic Vinyl Compounds: Experimental and Theoretical Kinetic Approaches | Zendy

Shahbakhsh Yaser | Zendy; HabibiKhorassani Sayyed Mostafa | Zendy; Shahraki Mehdi | Zendy

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Potassium Iodide as a New Nucleophilic Catalyst for the Novel Synthesis of Ionic Vinyl Compounds: Experimental and Theoretical Kinetic Approaches

Author(s) -

Shahbakhsh Yaser,

HabibiKhorassani Sayyed Mostafa,

Shahraki Mehdi

Publication year - 2020

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.202002224

Subject(s) - nucleophile , catalysis , chemistry , ionic liquid , ionic bonding , potassium , iodide , solvent , spectroscopy , reaction mechanism , nucleophilic substitution , nuclear magnetic resonance spectroscopy , inorganic chemistry , organic chemistry , ion , physics , quantum mechanics

In this work, for the first time, we introduce potassium iodide as a green, inexpensive, and widely available nucleophilic catalyst for the successful synthesis of an ionic vinyl compound. FT‐IR, 1 H NMR, 13 C NMR, energy‐dispersive spectroscopy (EDS), C, H, N elemental analysis and mass spectroscopy were used for the product characterization. The reaction mechanism investigated experimentally employing the UV‐vis method and theoretically at the M06‐2x/6‐31+G(d,p)‐dgdzvp levels of theory. Pure water and step 5 ‐ in which vinylic bond appears ‐ were kinetically recognized as the best solvent and R.D.S, respectively.

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