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Diaryl‐λ 3 ‐iodane Woven Supramolecular Architecture of Polyoxometalate
Author(s) -
Xiong Zhelun,
Wang Fang,
Ke Degang,
Wang Yu,
Huang Bo,
Xiao Zicheng,
Wu Pingfan
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202001599
Subject(s) - polyoxometalate , supramolecular chemistry , halogen , ion , chemistry , derivative (finance) , halogen bond , supramolecular assembly , materials science , nanotechnology , crystallography , molecule , organic chemistry , catalysis , alkyl , financial economics , economics
For the first time, diaryl‐λ 3 ‐iodane was employed as the cation of polyoxometalate (POM). The derivative exhibits a fascinating supramolecular architecture, which originates from halogen bonds between the cations and POM anion clusters. It is also the first proof of woven supramolecular architecture constructed by pure halogen bonds using POMs as multi‐dentate electron donors, providing a new vision for the design of POM‐based supramolecular architectures.