CO 2  Fixation into Cyclic Carbonates by a Zn‐Salen Based Conjugated Microporous Polymer | Zendy

Zhou Fuyu | Zendy; Deng Qiwen | Zendy; Huang Nianyu | Zendy; Zhou Wei | Zendy; Deng Weiqiao | Zendy

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CO 2 Fixation into Cyclic Carbonates by a Zn‐Salen Based Conjugated Microporous Polymer

Author(s) -

Zhou Fuyu,

Deng Qiwen,

Huang Nianyu,

Zhou Wei,

Deng Weiqiao

Publication year - 2020

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.202001538

Subject(s) - conjugated microporous polymer , microporous material , conjugated system , polymer , materials science , catalysis , sonogashira coupling , polymer chemistry , benzene , chemical engineering , chemistry , organic chemistry , palladium , engineering

Conjugated microporous Polymers (CMPs) are an emerging porous material with a high specific surface area, which has a wide range of applications in heterogeneous catalysis and gas separation etc. Here we report a new class of Zn‐salen based conjugated microporous polymer (Zn‐salen‐CMP) by Sonogashira‐Hagihara coupling reaction from the Zn‐salen compound and 1,3,5‐tris[4′‐(ethynyl)phenyl]benzene. The Zn‐salen‐CMP has extraordinary ability to capture and convert CO 2 into cyclic carbonates for up to 8 times repeated experiments without any influence on activity.

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