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Sole‐Component Visible Macrophotoinitiators with Si‐H: Decreased Oxygen Inhibition and Modified Cured Polymer Materials
Author(s) -
Wu Qingqing,
Liao Wen,
Wang Xiaoling,
Xiong Ying,
Tang Hongding
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202001069
Subject(s) - polymer , component (thermodynamics) , oxygen , materials science , chemical engineering , chemistry , polymer chemistry , polymer science , composite material , organic chemistry , engineering , physics , thermodynamics
Abstract Three polymethylhydrosiloxane (PMHS)‐modified thioxanthone (TX) visible macrophotoinitiators (TX‐PMHSs) were designed and prepared by the partially hydrosilylation of 2‐allyl(methyl)amino‐9H‐thioxanthen‐9‐one (TX−A) and PMHS. Their characteristics of photopolymerization, photolysis, reduction of oxygen inhibition and the modification of the polymer materials were discussed. As sole‐component visible photoinitiators, TX‐PMHSs could even initiate 1, 6‐hexanedioldiacrylate (HDDA) polymerization in the air atmosphere. Moreover, TX‐PMHSs changed the surface wettability property of the cured polyurethane diacrylate prepolymer (PUA) film, and improved the thermal stability of the polymer network. Thus, this work provided an efficient strategy to decrease oxygen inhibition and improve the cured polymer material properties.