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Photocatalytic Activity of Bi 2 O 3 Enhanced by the Addition of Ce 3+ /Ce 4+ Synthesized by Ethylene Glycol‐assisted Solvothermal Method
Author(s) -
Li Ting,
Quan Shanyu,
Shi Xuefeng,
Liu Cong,
Yang Linmei
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.202000951
Subject(s) - ethylene glycol , cerium , photocatalysis , electron paramagnetic resonance , oxygen , radical , photodegradation , nuclear chemistry , inorganic chemistry , adsorption , materials science , chemistry , photochemistry , catalysis , organic chemistry , physics , nuclear magnetic resonance
The photocatalysts Bi 2 O 3 :Ce 3+ /Ce 4+ (cerium content 0.2, 0.5, 0.8, and 1.1 wt. %) were prepared via one‐pot ethylene glycol‐assisted solvothermal method. The prepared x Ce‐Bi 2 O 3 (x =0.5, 0.8, 1.1) samples present δ‐Bi 2 O 3 phase with space group of Fm‐3 m at room temperature, which indicates that the high‐temperature cubic phase could be stabilized via Ce doping in Bi 2 O 3 lattices. Moreover, the addition of Ce 3+ /Ce 4+ could change the amount of oxygen vacancies (OVs) and adsorbed oxygen on the surface of photocatalysts. The existence of oxygen vacancies and adsorbed oxygen facilitated the generation of superoxide radicals () and hydroxide radicals (), which were the dominant reactive oxygen species for phenol degradation. The photocatalyst containing 0.8 wt. % cerium presented the highest photoactivity than the other synthesized samples. A photodegradation mechanism is proposed based on scavenger and electron spin resonance studies.