Copper‐Catalyzed  sp   3  ‐Carbon Radical/Halogen Radical Cross Coupling: Selective Halogenation of 1,3‐Dicarbonyl Compounds | Zendy

Lv ShuaiShuai | Zendy; Yan XuPing | Zendy; Li ChengKun | Zendy; Zhou ShaoFang | Zendy; Shoberu Adedamola | Zendy; Zou JianPing | Zendy

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Copper‐Catalyzed sp 3 ‐Carbon Radical/Halogen Radical Cross Coupling: Selective Halogenation of 1,3‐Dicarbonyl Compounds

Author(s) -

Lv ShuaiShuai,

Yan XuPing,

Li ChengKun,

Zhou ShaoFang,

Shoberu Adedamola,

Zou JianPing

Publication year - 2020

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.202000947

Subject(s) - halogenation , halogen , halide , chemistry , catalysis , copper , medicinal chemistry , coupling (piping) , carbon fibers , halocarbon , organic chemistry , materials science , alkyl , composite number , metallurgy , composite material

A new copper‐catalyzed sp 3 ‐carbon radical/halogen radical cross‐coupling strategy for the formation of C(sp 3 )‐X bond is described. This provides a general method for synthesis of α ‐halogenated and α , α ‐dihalogenated‐1,3‐dicarbonyl compounds using sodium halides as halogen source under mild conditions.

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