Two 3D Copper(II/I) Coordination Polymers: Structures, Energetic and Magnetic Properties | Zendy

Gao Wei | Zendy; Huang Hong | Zendy; Liu Feng | Zendy; Zhang Xiumei | Zendy; Liu Jieping | Zendy

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Two 3D Copper(II/I) Coordination Polymers: Structures, Energetic and Magnetic Properties

Author(s) -

Gao Wei,

Huang Hong,

Liu Feng,

Zhang Xiumei,

Liu Jieping

Publication year - 2020

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201904596

Subject(s) - antiferromagnetism , copper , coordination polymer , thermal stability , metal , topology (electrical circuits) , crystallography , crystal structure , polymer , materials science , chemistry , physics , metallurgy , organic chemistry , condensed matter physics , mathematics , combinatorics

Two copper compounds, [Cu II 4 (OH) 0.5 (MTZ) 2 (N 3 ) 5.5 (H 2 O) 0.5 ] n ( 1 ) and [Cu I (MTZ)] n ⋅0.17n(H 2 O) ( 2 ), [MTZ (5‐methyl tetrazolate) is generated by in situ hydro/solvothermal reaction], were prepared. Compound 1 shows a 3D structure with ((8 2 ⋅10) metal topology and exhibits antiferromagnetic interactions through the complicated EO‐N 3 , μ 2 ‐OH and μ‐N,N‐tetrazolate bridges. Compound 2 also displays a 3D structure with (8 3 ) metal topology, which shows good thermal stability and potential high‐energetic properties.

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