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Transition‐Metal‐Free Cross‐Coupling of Arylsilanes with DAST Reagent: Synthesis of Aromatic Sulfinamides
Author(s) -
Liu Zhenwei,
Liu Xinya,
Luan Nannan,
Geng Yang,
Liang Apeng,
Li Jingya,
Zou Dapeng,
Wu Yusheng,
Wu Yangjie
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201904464
Subject(s) - reagent , chemistry , substrate (aquarium) , scope (computer science) , transition metal , combinatorial chemistry , coupling (piping) , organic chemistry , materials science , catalysis , computer science , metallurgy , oceanography , programming language , geology
A transition‐metal‐free cross‐coupling of arylsilanes with DAST (diethylaminosulfur trifluoride) reagent has been developed. A number of aromatic sulfinamides were obtained in reasonable yields (15%‐87%). Notable advantages of this method include easy operation, mild reaction conditions and wide substrate scope.