Premium
Facile Synthetic Route for Direct Access of Perylenediimide Single Crystals in High Yield through In Situ Crystallization
Author(s) -
Pitchaimani Jayaraman,
Kundu Anu,
Anthony Savarimuthu Philip,
Moon Dohyun,
Madhu Vedichi
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201904347
Subject(s) - crystallization , yield (engineering) , materials science , stacking , in situ , chemical engineering , crystallography , crystal (programming language) , absorption (acoustics) , chemistry , organic chemistry , composite material , computer science , engineering , programming language
Synthetic protocol for direct growth of perylenediimides (PDIs) single crystals in high yield via temperature‐driven in situ crystallization has been established. Single crystal analysis confirmed the formation of 1D column of PDIs that are stabilized by π‐π stacking and C−H⋅⋅⋅O hydrogen bonding interactions. The influence of reaction temperature on the crystallization, absorption and fluorescence properties of PDIs has been studied.