Catalyst‐Free α‐Aminoxylation of 1,3‐Dicarbonyl Compounds with TEMPO Using Selectfluor as an Oxidant | Zendy

Tang Lin | Zendy; Yang Zhen | Zendy; Yang Fang | Zendy; Huang Yifan | Zendy; Chen Hanfei | Zendy; Cheng Hao | Zendy; Song Weiyan | Zendy; Ren Bo | Zendy; Zhou Qiuju | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Catalyst‐Free α‐Aminoxylation of 1,3‐Dicarbonyl Compounds with TEMPO Using Selectfluor as an Oxidant

Author(s) -

Tang Lin,

Yang Zhen,

Yang Fang,

Huang Yifan,

Chen Hanfei,

Cheng Hao,

Song Weiyan,

Ren Bo,

Zhou Qiuju

Publication year - 2019

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201903856

Subject(s) - selectfluor , catalysis , regioselectivity , substrate (aquarium) , chemistry , combinatorial chemistry , reaction conditions , organic chemistry , biology , ecology

A catalyst‐free and regioselective α‐aminoxylation of 1,3‐dicarbonyl compounds with TEMPO by use of Selectfluor as a mild oxidant has been demonstrated, yielding the corresponding alkoxyamines in good to excellent yields. The developed protocol features no employment of a catalyst, broad substrate scope and mild reaction conditions, which enables a convenient and efficient avenue for quaternary C–O bond formation.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research