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Silver‐Catalyzed Synthesis of Enones/α‐Iodoenones from Tertiary Propargyl Alcohols
Author(s) -
Naveen Naganaboina,
Ramesh Golla,
Balamurugan Rengarajan
Publication year - 2019
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201903568
Subject(s) - propargyl , catalysis , tertiary alcohols , chemistry , medicinal chemistry , tetra , organic chemistry
Tertiary propargyl alcohols undergo smooth Meyer‐Schuster rearrangement to give enones in the presence of silver catalyst alone at room temperature. The intermediate can be trapped using NIS to make useful tetra substituted α‐iodoenones.