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Jatropha Oil Cake Based Activated Carbon for Symmetric Supercapacitor Application: A Comparative Study on Conventional and Hydrothermal Carbonization Processes
Author(s) -
Siva Sankari M.,
Vivekanandhan S.
Publication year - 2020
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201903492
Subject(s) - supercapacitor , hydrothermal carbonization , carbonization , activated carbon , materials science , specific surface area , chemical engineering , bet theory , hydrothermal circulation , carbon fibers , electrochemistry , chemistry , electrode , scanning electron microscope , organic chemistry , composite material , adsorption , catalysis , composite number , engineering
Jatropha oilcake (JOC), a major agro industrial co‐product was effectively converted into activated carbons employing KOH mediated chemical process for supercapacitor applications. The activated carbons were synthesized by employing conventional (CC) as well as hydrothermal carbonization (HTC) processes and investigated their impact on their physicochemical properties. The graphitization degree of the pristine and activated biocarbons was investigated through XRD and RAMAN analysis. BET surface area analysis showed the enhanced specific surface area of the pristine carbons from 71.5 (CC) and 48.1 (HTC) m 2 /g into 678.1 (CC) and 746.7 m 2 /g (HTC) through KOH activation. The synthesized activated biocarbon materials were explored as the electrode material for supercapacitors. The electrochemical analysis of the fabricated symmetric supercapacitor showed the specific capacitance of 145.76 F/g and 174.78 F/g at 1 A/g for the activated biocarbons obtained respectively through conventional and hydrothermal carbonization processes. Also, they showed considerable energy density of 5.28 Whkg −1 (CC) and 6.49 Whkg −1 (HTC) at a power density of 248.6 and 265.09 W kg −1 . Among the two different approaches, the hydrothermal process showed great promise for the production of renewable biomass‐derived activated biocarbon materials for supercapacitor applications.