Highly Efficient and Chemoselective Reduction of Nitroarenes Using Hybrid Ni@g‐C 3 N 4  as Reusable Catalyst | Zendy

Payra Soumen | Zendy; Banerjee Subhash | Zendy

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Highly Efficient and Chemoselective Reduction of Nitroarenes Using Hybrid Ni@g‐C 3 N 4 as Reusable Catalyst

Author(s) -

Payra Soumen,

Banerjee Subhash

Publication year - 2019

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201902854

Subject(s) - catalysis , dissociation (chemistry) , nanoparticle , hydrogen , nitrogen , chemistry , combinatorial chemistry , nickel , chemical engineering , materials science , inorganic chemistry , nuclear chemistry , nanotechnology , organic chemistry , engineering

Hybrid Ni@g‐C 3 N 4 ‐catalyzed highly chemoselective reduction of nitroarenes with high turnover frequency has been demonstrated using NaBH 4 as source of hydrogen. Here, g‐C 3 N 4 provides excellent stability to Ni(0) nanoparticles on its nitrogen rich surface and also facilitates the dissociation of NaBH 4 resulting formation of active Νi‐H + and Νi‐H ‐ via cooperative effect.

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