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Monodispersed Zerovalent Iron Nanoparticles Decorated Carbon Submicrospheres for Enhanced Removal of DDT from Aqueous Solutions
Author(s) -
Kang Shenghong,
Wang Guozhong,
Wang Zhaoming,
Cai Weiping
Publication year - 2019
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201902837
Subject(s) - zerovalent iron , aqueous solution , adsorption , nanoparticle , chemical engineering , materials science , carbon fibers , chemistry , nanocomposite , nanotechnology , composite material , organic chemistry , composite number , engineering
A simple route is presented to fabricate the nano zero‐valent iron/carbon sphere (nZVI/CSs) composites via Fe 2+ ion‐adsorption and then reduction reaction on the pre‐prepared CSs. The nZVI/CSs composites with monodispersed nZVI particles are successfully fabricated. The monodispersed nZVI particles with 30–50 nm in size are uniformly decorated on the sub‐microsized CSs with about 250 nm in diameter. These nZVI/CSs composites are of enough high specific surface area (about 55.8 m 2 ⋅g −1 ) and good ferromagnetism. Importantly, such nZVI/CSs have exhibited significantly stronger and faster removal performances to the organic pollutants compared with the pure nZVI and pure CSs, in addition to the easy separation from solutions. Typically, in the DDT [or 1,1,1‐trichloro‐2, 2‐bis(4‐chlorophenyl)ethane] aqueous solution with 10 ppm, more than 95% of DDT content can be removed within 140 min after adding 1.0 g⋅L −1 nZVI/CSs. The capacity of removal is up to 15.6 mg⋅g −1 , remarkably larger than the previously reported one (2.5 mg⋅g −1 ) by carbon nanotubes. This is attributed to the synergistic effects from the CSs’ high adsorptivity and nZVI's strong reducibility. This study not only provides a new candidate material for the treatment of the DDT‐polluted environments, but also deepens understanding the process of DDT removal.