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Acidic Handle Assemble Heterogeneous Carbocatalyst for Facile Aliphatic Nucleophilic Fluorination
Author(s) -
Said Madhukar S.,
Pandole Satish,
Suryavanshi Amol,
Kumar Pradeep,
Gajbhiye Jayan M.
Publication year - 2019
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201902771
Subject(s) - nucleophile , sulfonate , catalysis , halide , yield (engineering) , fluoride , chemistry , alkyl , metal , organic chemistry , fluorine , inorganic chemistry , materials science , sodium , metallurgy
Acidic handle (‐SO 3 H) assemble carbonaceous catalyst synthesized from glucose acts as a modulator for the nucleophilic fluorination reaction. The heterogeneous catalyst works with various alkyl sulfonate, halide and metal fluoride (MF), to offer a high yield of fluorinated products up to 93%. This carbonaceous catalyst is recyclable for more than five times, with no major loss of activity.