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Schiff Base/CuI as a Novel Efficient Catalyst System for Cu–Catalyzed Heck Reaction in Water
Author(s) -
Wang Yufang,
Zhang Mingjie
Publication year - 2019
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201902575
Subject(s) - catalysis , schiff base , heck reaction , aryl , chemistry , ligand (biochemistry) , piperidine , base (topology) , organic chemistry , polymer chemistry , combinatorial chemistry , medicinal chemistry , palladium , alkyl , mathematical analysis , biochemistry , receptor , mathematics
A novel efficient phosphorus free ligand Schiff base 5‐tert‐butyl‐3‐(piperidine methyl) salicylaldimine has been developed for the Cu‐catalyzed Heck reaction in neat water. Both aryl bromides and electron‐deficient aryl chlorides could proceed smoothly with moderate to excellent yields. The catalyst system is reusable.