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One‐Pot Catalytic Synthesis of Aniline‐Copolymer‐Containing Reactive Aldehyde Groups Using a Laccase‐Mediator System
Author(s) -
Khlupova Maria,
Morozova Olga,
Shumakovich Galina,
Vasil'eva Irina,
Zaitseva Elena,
Yaropolov Alexander
Publication year - 2019
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201902403
Subject(s) - laccase , copolymer , aniline , aldehyde , chemistry , organic chemistry , catalysis , alcohol , phenylalanine , mediator , combinatorial chemistry , polymer chemistry , enzyme , polymer , biochemistry , amino acid , medicine
Laccase‐mediator systems (LMS) are extensively used both for degradation of various xenobiotics and synthesis of new compounds. In this work a laccase‐mediator system was applied to copolymerization of aniline and 2‐aminophenythyl alcohol on a ‘soft’ poly(2‐acrylamido‐2‐methyl‐1‐propansulfonic acid) (PAMPS) template. The one‐pot biocatalytic reaction resulted in obtaining a conducting copolymer/PAMPS complex with reactive aldehyde groups which enabled grafting the physiologically active compound 3,4‐dihydroxy‐L‐phenylalanine (DOPA) to it.