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Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl‐(1‐propylbenzimidazol‐2‐yl)methanol
Author(s) -
Burlov Anatolii S.,
Koshchienko Yurii V.,
Vlasenko Valery G.,
Bogomyakov Artem S.,
Kolodina Alexandra A.,
Zubavichus Yan V.,
Lazarenko Vladimir A.,
Khrustalev Victor N.
Publication year - 2019
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201901186
Subject(s) - copper , antiferromagnetism , chemistry , denticity , methanol , crystal structure , ligand (biochemistry) , crystallography , inorganic chemistry , organic chemistry , receptor , biochemistry , physics , condensed matter physics
Two types of binuclear copper complexes [LCuN 3 ] 2 and [LCuNO 3 ] 2 .of bidentate ligand ‐ diphenyl‐(1‐propylbenzimidazol‐2‐yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu 2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.