Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl‐(1‐propylbenzimidazol‐2‐yl)methanol | Zendy

Burlov Anatolii S. | Zendy; Koshchienko Yurii V. | Zendy; Vlasenko Valery G. | Zendy; Bogomyakov Artem S. | Zendy; Kolodina Alexandra A. | Zendy; Zubavichus Yan V. | Zendy; Lazarenko Vladimir A. | Zendy; Khrustalev Victor N. | Zendy

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Synthesis, Structure and Magnetic Properties of Copper(II) Complexes of Diphenyl‐(1‐propylbenzimidazol‐2‐yl)methanol

Author(s) -

Burlov Anatolii S.,

Koshchienko Yurii V.,

Vlasenko Valery G.,

Bogomyakov Artem S.,

Kolodina Alexandra A.,

Zubavichus Yan V.,

Lazarenko Vladimir A.,

Khrustalev Victor N.

Publication year - 2019

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201901186

Subject(s) - copper , antiferromagnetism , chemistry , denticity , methanol , crystal structure , ligand (biochemistry) , crystallography , inorganic chemistry , organic chemistry , receptor , biochemistry , physics , condensed matter physics

Two types of binuclear copper complexes [LCuN 3 ] 2 and [LCuNO 3 ] 2 .of bidentate ligand ‐ diphenyl‐(1‐propylbenzimidazol‐2‐yl)methanol (HL) in the 4:1 ratio were synthesized. The crystal structure of copper complexes shows a centrosymmetric dimeric binuclear complex with two Cu 2+ cations bridged by two oxygen atoms from two organic ligands. In the complexes, a very strong antiferromagnetic exchange interaction between copper atoms is observed.

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