Rubidium Cerium (IV) Iodates with High UV‐Light‐Driven Photocatalytic Efficiency | Zendy

Tang Changcheng | Zendy; Jiang Xingxing | Zendy; Yin Wenlong | Zendy; Chen Fang | Zendy; Guo Shu | Zendy; Song Gaomin | Zendy; Liu Lijuan | Zendy; Huang Hongwei | Zendy; Xia Mingjun | Zendy; Lin Zheshuai | Zendy; Wang Xiaoyang | Zendy

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Rubidium Cerium (IV) Iodates with High UV‐Light‐Driven Photocatalytic Efficiency

Author(s) -

Tang Changcheng,

Jiang Xingxing,

Yin Wenlong,

Chen Fang,

Guo Shu,

Song Gaomin,

Liu Lijuan,

Huang Hongwei,

Xia Mingjun,

Lin Zheshuai,

Wang Xiaoyang

Publication year - 2019

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201901176

Subject(s) - cerium , photocatalysis , rubidium , hydrothermal circulation , methyl orange , reactivity (psychology) , irradiation , diffuse reflection , nuclear chemistry , chemistry , photochemistry , materials science , inorganic chemistry , catalysis , chemical engineering , potassium , organic chemistry , physics , optics , medicine , alternative medicine , pathology , nuclear physics , engineering

Two new rubidium cerium (IV) iodates, namely RbCeI 5 O 15 and RbCeI 5 O 15 ⋅H 2 O, have been synthesized through hydrothermal reactions. Both compounds are composed of [CeO 8 ], [RbO 8 ] polyhedrons, and [IO 3 ] umbrella‐like groups, with RbCeI 5 O 15 ⋅H 2 O having an additional [H 2 O] group attached to the Ce atom. UV‐vis‐NIR diffuse reflectance spectrum indicates that the band gap of RbCeI 5 O 15 ⋅H 2 O is 2.76 eV. RbCeI 5 O 15 ⋅H 2 O shows high photocatalytic reactivity in the degradation of methyl orange (MO) under UV light irradiation.

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