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MoS 2 Nanosheets Anchored on Melamine‐Sponges‐Derived Nitrogen‐Doped Carbon Microtubes as Anode for High‐Rate Sodium‐Ion Batteries
Author(s) -
Feng Meng,
Zhang Huizhen,
Zhang Yuchan,
Zhang Mengjie,
Feng Hongbin
Publication year - 2019
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201900660
Subject(s) - anode , melamine , materials science , faraday efficiency , electrochemistry , electrode , carbon fibers , chemical engineering , sodium , doping , nitrogen , ion , nanotechnology , composite number , composite material , chemistry , optoelectronics , organic chemistry , metallurgy , engineering
Here we demonstrate the design and synthesis of a composite electrode material consisting of MoS 2 nanosheets anchored on nitrogen‐doped (N‐doped) carbon microtubes (NCMT) for anode applications in sodium‐ion batteries (SIBs). The NCMT skeleton was derived from the common melamine sponges, which was used not only as a template but also as the source of nitrogen and carbon. This smart design can effectively shorten the diffusion length of Na + ions, increase electric conductivity of the electrode, and provide more active sites for electrochemical reactions. When evaluated as anode for sodium‐ion batteries, the MoS 2 @NCMT composites exhibited a larger initial coulombic efficiency (67.9%), high rate capability (196 mA h g −1 at 10 A g −1 and 118 mA h g −1 at 30 A g −1 ) and better cycling stability (289 mA h g −1 after 100 cycles at 80 mA g −1 ).