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Bioinspired First Stereoselective Total Synthesis of Spinosulfate B
Author(s) -
Bokam Ramesh,
Annam S. CH. V. Appa Rao,
Yalavarthi Nageswara Rao,
Gundoju Narayanarao,
Ponnapalli Mangala Gowri
Publication year - 2019
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201900396
Subject(s) - stereoselectivity , stille reaction , total synthesis , kinetic resolution , chemistry , metathesis , stereochemistry , olefin fiber , hydrolysis , olefin metathesis , combinatorial chemistry , organic chemistry , enantioselective synthesis , catalysis , polymerization , polymer
An efficient bioinspired stereoselective first total synthesis of spinosulfate B has been accomplished following Jacobsen's hydrolytic kinetic resolution, Stille coupling, olefin‐cross metathesis (OCM), Horner Wadsworth Emmons olefination, and De Brabander's esterification as key steps.