Bioinspired First Stereoselective Total Synthesis of Spinosulfate B | Zendy

Bokam Ramesh | Zendy; Annam S. CH. V. Appa Rao | Zendy; Yalavarthi Nageswara Rao | Zendy; Gundoju Narayanarao | Zendy; Ponnapalli Mangala Gowri | Zendy

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Bioinspired First Stereoselective Total Synthesis of Spinosulfate B

Author(s) -

Bokam Ramesh,

Annam S. CH. V. Appa Rao,

Yalavarthi Nageswara Rao,

Gundoju Narayanarao,

Ponnapalli Mangala Gowri

Publication year - 2019

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201900396

Subject(s) - stereoselectivity , stille reaction , total synthesis , kinetic resolution , chemistry , metathesis , stereochemistry , olefin fiber , hydrolysis , olefin metathesis , combinatorial chemistry , organic chemistry , enantioselective synthesis , catalysis , polymerization , polymer

An efficient bioinspired stereoselective first total synthesis of spinosulfate B has been accomplished following Jacobsen's hydrolytic kinetic resolution, Stille coupling, olefin‐cross metathesis (OCM), Horner Wadsworth Emmons olefination, and De Brabander's esterification as key steps.

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