Rhodium‐Catalyzed Mild C7‐Amination of Indolines with Nitrosobenzenes | Zendy

Xiong Dan | Zendy; Wang Lianhui | Zendy; Jie Lianghua | Zendy; Yang Zi | Zendy; Li Lulin | Zendy; Cui Xiuling | Zendy

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Rhodium‐Catalyzed Mild C7‐Amination of Indolines with Nitrosobenzenes

Author(s) -

Xiong Dan,

Wang Lianhui,

Jie Lianghua,

Yang Zi,

Li Lulin,

Cui Xiuling

Publication year - 2018

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201803692

Subject(s) - amination , rhodium , catalysis , nitrogen atom , functional group , atom economy , chemistry , transformation (genetics) , combinatorial chemistry , group (periodic table) , organic chemistry , polymer , biochemistry , gene

A mild and practical Rh(III)‐catalyzed C 7 –H amination of indolines has been described, which allows the synthesis of a variety of 7‐amino‐substituted indolines with good functional group tolerance and high atom economy. Notably, nitrosobenzenes serve as nitrogen source in this transformation, and therefore behave environmentally friendly for C−N bond constructions.

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