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Rhodium‐Catalyzed Mild C7‐Amination of Indolines with Nitrosobenzenes
Author(s) -
Xiong Dan,
Wang Lianhui,
Jie Lianghua,
Yang Zi,
Li Lulin,
Cui Xiuling
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201803692
Subject(s) - amination , rhodium , catalysis , nitrogen atom , functional group , atom economy , chemistry , transformation (genetics) , combinatorial chemistry , group (periodic table) , organic chemistry , polymer , biochemistry , gene
A mild and practical Rh(III)‐catalyzed C 7 –H amination of indolines has been described, which allows the synthesis of a variety of 7‐amino‐substituted indolines with good functional group tolerance and high atom economy. Notably, nitrosobenzenes serve as nitrogen source in this transformation, and therefore behave environmentally friendly for C−N bond constructions.