Palladium‐Catalyzed Regioselective C‐H Bond  ortho ‐Acetylation and Oxidative Homocoupling of  N ‐Arylcarbamates | Zendy

Dabiri Minoo | Zendy; Osmani Chiman | Zendy; Nikbakht Roonak | Zendy; Movahed Siyavash Kazemi | Zendy

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Palladium‐Catalyzed Regioselective C‐H Bond ortho ‐Acetylation and Oxidative Homocoupling of N ‐Arylcarbamates

Author(s) -

Dabiri Minoo,

Osmani Chiman,

Nikbakht Roonak,

Movahed Siyavash Kazemi

Publication year - 2019

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201803053

Subject(s) - regioselectivity , chemistry , catalysis , oxidative phosphorylation , acetylation , palladium , medicinal chemistry , surface modification , combinatorial chemistry , organic chemistry , biochemistry , gene

An efficient and straightforward protocol for the regioselective acyloxylation of N ‐arylarbamates via Pd‐catalyzed C−H bond functionalization has been demonstrated. The aliphatic and benzoic acid derivatives were used as the acyloxyl source to convert aromatic sp 2 C−H bonds into C−O bonds. Additionally, the oxidative homocoupling of N ‐arylarbamates were evaluated and gave the corresponding homocoupled products in good yields.

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