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A New Resin Containing Aminopropylphosphonate Chelating Ligand for High‐Performance Mitigation of Heavy Metal Ions
Author(s) -
Kazi Izzat W.,
Ullah Nisar,
Ali Shaikh A.
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201803045
Subject(s) - adsorption , sorbent , aqueous solution , chemistry , metal ions in aqueous solution , desorption , endothermic process , metal , chelating resin , langmuir adsorption model , chelation , inorganic chemistry , diffusion , ligand (biochemistry) , nuclear chemistry , organic chemistry , biochemistry , physics , receptor , thermodynamics
Cyclopolymerization, initiated by t‐butylhydroperoxide, of an aqueous solution of N ‐(3‐phosphonopropyl)diallylammonium hydrochloride and cross‐linker tetraallylpiperazinium dichloride in 9:1 mol ratio, led to a pH‐responsive cross‐linked resin (80% yield). The resin showed exceptional efficiency for entrapping toxic metal ions from aqueous systems. Using Langmuir adsorption isotherm, the respective maximum uptake ( Q m ) of Pb 2+ and Cu 2+ ions was determined to be 7.18 and 6.76 mmol g −1 . The very impressive performance accorded the resin a prestigious place among many sorbents in recent works. The adsorption data fitted second‐order kinetics with respective E a of 35.5 and 31.1 kJ mol −1 for Pb 2+ and Cu 2+ ions. While the initial rapid adsorption of metal ions was due to film diffusion, the slower adsorption followed intraparticle diffusion. SEM and EDX analyses confirmed the metal ions’ adsorption onto sorbent. The negative Δ G ° and positive Δ H ° values demonstrated the endothermic adsorption as a favorable process. The sorbent is recyclable as evinced by the excellent adsorption/desorption process.