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Supramolecular Architectures of Polyoxometalate Hybrids Originating from Halogen and Hydrogen‐Bonding Interactions
Author(s) -
Lin Xinjun,
Huang Bo,
Xiong Zhelun,
Fang Ting,
Zhang Xiaoxiao,
Xiao Zicheng,
Wu Pingfan
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201802912
Subject(s) - polyoxometalate , halogen , halogen bond , hydrogen bond , supramolecular chemistry , covalent bond , chemistry , crystallography , materials science , inorganic chemistry , polymer chemistry , molecule , organic chemistry , catalysis , crystal structure , alkyl
In this paper, we explored the possibility of building halogen bonds between polyoxometalate anions by synthesizing a series of polyoxometalate clusters covalently linked to different halogen atoms. Among these samples, the polyoxometalate hybrids containing bromide and iodine atoms exhibited both halogen and hydrogen bonding interactions between the hybrid anions, leading to novel 3D framework assemblies.