Three‐Dimensional Metal‐Organic Polymer of Multivalent Hexaphenylbenzene | Zendy

Madhu Suresh | Zendy; Gonnade Rajesh G. | Zendy; Sanjayan Gangadhar J. | Zendy

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Three‐Dimensional Metal‐Organic Polymer of Multivalent Hexaphenylbenzene

Author(s) -

Madhu Suresh,

Gonnade Rajesh G.,

Sanjayan Gangadhar J.

Publication year - 2018

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201802797

Subject(s) - metal organic framework , thermogravimetric analysis , ligand (biochemistry) , infrared spectroscopy , chemistry , metal , molecule , polymer chemistry , polymer , aryl , materials science , organic chemistry , biochemistry , alkyl , receptor , adsorption

Metal‐Organic Frameworks(MOFs) synthesized from ligands more than ten co‐ordinating sites may offer material applications due to their structural architecture. Herein, a synthesis of metal‐organic framework is reported from a ligand featuring 12‐aryl carboxylic acid groups appended on a hexaphenylbenzene and s‐block element potassium. The synthesized MOF was characterized by thermogravimetric analysis, infrared spectroscopy and X‐diffraction studies. The X‐ray crystal structure of MOF was shown to have a significant number of trapped and coordinated water molecules in its three‐dimensional framework.

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