One‐step Modification of Active Sites and Support in Ni/Al 2 O 3 Catalyst for Hydrodeoxygenation of Lignin‐derived Diphenyl Ether

A bifunctional Ni 2 Si/SiO 2 ‐Al 2 O 3 catalyst was prepared by one‐step chemical vapor deposition (CVD), and used for hydrode‐oxygenation (HDO) of diphenyl ether (DPE). During the one‐step CVD process, metallic Ni species as the HDO active sites were isolated by intermetallic modification of Si atoms and partial electron transferred from Ni to Si, as inferred by XRD, XPS, and theoretical calculation. Furthermore, the characterization results revealed that the acidity and structure of Al 2 O 3 were tuned due to the formation of Al‐O−Si bonds. Consequently, compared with Ni/Al 2 O 3 catalyst, the Ni 2 Si/SiO 2 ‐Al 2 O 3 catalyst showed a higher benzene selectivity (60% vs 47%), O‐free products selectivity at the similar conversion of DPE, and high stability for the HDO of DPE. This work provides insight for design of bifunctional catalysts with specific catalytic properties by one‐step CVD method.