Synthesis, Structure and Catalytic Oxidation of Ruthenium(III) Complexes Containing 1‐(Arylazo)naphthol Ligands Derived from  β −Naphthol and Sterically Bulky Amines | Zendy

Thirumal Muniyappan | Zendy; Ramesh Madhan | Zendy; Kaleeswaran Dhananjayan | Zendy; Venkatachalam Galmari speac | Zendy

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Synthesis, Structure and Catalytic Oxidation of Ruthenium(III) Complexes Containing 1‐(Arylazo)naphthol Ligands Derived from β −Naphthol and Sterically Bulky Amines

Author(s) -

Thirumal Muniyappan,

Ramesh Madhan,

Kaleeswaran Dhananjayan,

Venkatachalam Galmari speac

Publication year - 2018

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201802340

Subject(s) - ruthenium , chemistry , electron paramagnetic resonance , catalysis , steric effects , fourier transform infrared spectroscopy , photochemistry , infrared , polymer chemistry , medicinal chemistry , organic chemistry , physics , nuclear magnetic resonance , quantum mechanics , optics

A new class of ruthenium(III) complexes containing O, N donor functionalized azo derivatives were designed and synthesized. The synthesized compounds were characterized by fourier‐transform infrared (FTIR), ultraviolet–visible (UV‐vis) and electron paramagnetic resonance ( EPR) spectral studies. The X−ray crystal structure of one of the complexes [Ru(L 1 ) 3 ] 1 has been determined. The catalytic activity of the complex [Ru(L 1 ) 3 ] 1 has been studied for the oxidation of primary and secondary alcohols to corresponding carbonyl compounds in the presence of N‐ Methylmorpholine‐ N ‐Oxide as co‐oxidant.

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