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One Ni(II) Polymer with Fluorescent Response Based on Mixed Ligands
Author(s) -
Yin XiuJu,
Zhu LongGuan
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201802186
Subject(s) - monoclinic crystal system , fluorescence , polymer , thermal stability , nickel , fourier transform infrared spectroscopy , chemistry , benzoic acid , crystallography , diffraction , elemental analysis , thermal analysis , nuclear chemistry , materials science , crystal structure , analytical chemistry (journal) , thermal , inorganic chemistry , organic chemistry , physics , optics , meteorology
One new nickel polymer [Ni(L) 2 ⋅(3‐Sb)] n ( 1 ) (L=2‐pyrimidinecarboximidamide; 3‐Sb=3‐sulfo‐benzoic acid) has been synthesized and it is characterized by single‐crystal X‐ray diffraction, FTIR and elemental analysis. The results show that polymer 1 belongs to the monoclinic system, P 2 1 /n space group, with a =11.3572(8), b =13.1745(8), c =13.2345(9) Å, β =98.887(6)°, V =1956.4(2) Å 3 , Mr=535.13. TGA shows that polymer 1 began to decompose at 230 C, which indicates 1 have good thermal stability. The fluorescence analysis of 1 in the solid state at room temperature shows that this new Ni(II) polymer material has good fluorescence response.