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Palladium‐Catalyzed Ligand‐Free Suzuki–Miyaura Reaction of Aryl Fluorosulfates and Various Arylboron Compounds
Author(s) -
Li Xinmin,
Zhang Hang,
Feng Fangfang,
Hu Qinghong,
Yuan Zeli
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201802120
Subject(s) - palladium , aryl , catalysis , ligand (biochemistry) , chemistry , combinatorial chemistry , coupling reaction , tandem , suzuki reaction , reaction conditions , organic chemistry , materials science , receptor , biochemistry , alkyl , composite material
A practical and efficient protocol for the synthesis of biaryl products in good yields by a ligand‐free palladium catalyzed Suzuki–Miyaura reaction of aryl fluorosulfates and various arylboron compounds has been developed. Moreover, we report a one‐pot tandem method for conversion of phenol derivatives to aryl fluorosulfates, and subsequent cross‐coupling to form biaryls.