I 2 /K 2 S 2 O 8 : An Unprecedented Deoxygenating System for N‐Oxides and Sulfoxides | Zendy

Raghuvanshi Dushyant Singh | Zendy; Verma Narsingh | Zendy; Gupta Atul | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

I 2 /K 2 S 2 O 8 : An Unprecedented Deoxygenating System for N‐Oxides and Sulfoxides

Author(s) -

Raghuvanshi Dushyant Singh,

Verma Narsingh,

Gupta Atul

Publication year - 2019

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201801838

Subject(s) - deoxygenation , reagent , quinoline , aryl , chemistry , oxide , pyridine , metal , amine gas treating , medicinal chemistry , inorganic chemistry , organic chemistry , catalysis , alkyl

A novel and efficient metal‐free approach has been disclosed for the deoxygenation of amine N‐oxides to amines and sulfoxides to corresponding sulfides using the green and economical reagent I 2 /K 2 S 2 O 8 . Deoxygenation of pyridine N‐oxide, quinoline N‐oxide, N , N ‐dialkylaniline N‐oxides, trialkylamine N‐oxides and aryl sulfoxides have been achieved in excellent yields. This method has been proven to be applicable to a wide range of substrates. A broad range of functional groups were well tolerated in this reaction system.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research