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Eco‐Friendly C–I and C–O Bond Formation of Simple Alkenes: Direct Access to β ‐Iodo Oxyamines
Author(s) -
Sun Kai,
Zhang Saifei,
Liu Zhenhua,
Lv Yunhe
Publication year - 2018
Publication title -
chemistryselect
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.437
H-Index - 34
ISSN - 2365-6549
DOI - 10.1002/slct.201800878
Subject(s) - simple (philosophy) , heteroatom , derivatization , iodine , chemistry , substrate (aquarium) , environmentally friendly , scope (computer science) , combinatorial chemistry , computational chemistry , organic chemistry , computer science , ring (chemistry) , philosophy , ecology , epistemology , biology , oceanography , high performance liquid chromatography , programming language , geology
A protocol has been established for iodine‐mediated C–I and C–O bond formation of alkenes, including vinylarenes, allylbenzenes, and simple heteroatom‐bearing cyclo‐ and linear alkenes. The approach provides a simple route to a series of structurally diverse β ‐iodo oxyamines in moderate to excellent yields. The broad substrate scope, ease of large‐scale preparation, and potential for derivatization make this reaction attractive.